108452-14-8

Basic information

• Product Name: (C₆H₅)2POH(BH₃)
• Synonyms: (C₆H₅)2POH(BH₃)
• CAS NO: 108452-14-8
• Molecular Weight: 216.027
• Mol File: 108452-14-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (C₆H₅)2POH(BH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)2POH(BH₃)(108452-14-8)
• EPA Substance Registry System: (C₆H₅)2POH(BH₃)(108452-14-8)

Safety Data

• Hazardous Substances Data: 108452-14-8(Hazardous Substances Data)

Upstream product

• 12081-54-8 tetraethyldiborane⁽⁶⁾ 
• 108342-97-8 (diphenylphosphinooxy)diethylborane 
• 14044-65-6 borane-THF 
• 4559-70-0 Diphenylphosphine oxide 

Relevant articles and documents

Direct conversion of sec-phosphine oxides to sec-phosphine-boranes using BH3

An effective and mild synthetic method for secondary phosphine-boranes from secondary phosphine oxides was developed. The slow addition of borane-tetrahydrofuran to a solution of secondary phosphine oxides at ambient temperature gave secondary phosphine-boranes with high yield. The use of air-sensitive secondary phosphines, which are common substrates for secondary phosphine-borane syntheses, is avoided in this mild process. Moreover, generation of by-products, such as secondary hydroxy-phosphine-boranes, is also minimized.