108583-40-0

Basic information

• Product Name: 2-acetyl-3-phenyl-4-ethoxycarbonyl-2,3-diaza<3.3.3>propellane
• CAS NO: 108583-40-0
• Molecular Weight: 342.438
• Mol File: 108583-40-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetyl-3-phenyl-4-ethoxycarbonyl-2,3-diaza<3.3.3>propellane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetyl-3-phenyl-4-ethoxycarbonyl-2,3-diaza<3.3.3>propellane(108583-40-0)
• EPA Substance Registry System: 2-acetyl-3-phenyl-4-ethoxycarbonyl-2,3-diaza<3.3.3>propellane(108583-40-0)

Safety Data

• Hazardous Substances Data: 108583-40-0(Hazardous Substances Data)

Upstream product

• 100-63-0 phenylhydrazine 
• 108583-37-5 [5-(Phenyl-hydrazono)-cyclooctylidene]-acetic acid ethyl ester 
• 108583-30-8 5-ethoxycarbonylmethylene-cyclooctanone 
• 1489-74-3 cyclooctane-1,5-dione 

Relevant articles and documents

SYNTHESYS OF HETEROCYCLIC PROPELLANES. PREPARATION AND TRANSANNULAR REACTIONS OF 5-ETHOXYCARBONYLMETHYLENE-CYCLOOCTANONE AND CORRESPONDING OXIMES AND HYDRAZONES

5-Ethoxycarbonylmethylene-cyclooctanone (3) is prepared by Wittig monoolefination of dione 1 with phosphorus ylide 2.Thermal transannular cyclization of oxime 6 and phenylhydrazone 12 of the ketone 3 affords 3-oxa-2-aza- and 2,3-diazapropellanes 7 and 14 respectively.Irradiation of ketone 3, its oxime 9, and its dimethylhydrazone 16 furnish 9-oxa-, and 9-azapropellanes 11, 10, and 17, respectively.In addition to the propellane 14, phenylazobicyclo compound 13 is also obtained from phenylhydrozyne 12.The acetyl derivatives 8 and 15 of propellanes 7 and 14 are also prepared and studied.