1085938-08-4Relevant articles and documents
Cyclooctyne [60]fullerene hexakis adducts: A globular scaffold for copper-free click chemistry
Ramos-Soriano, Javier,Reina, José J.,Pérez-Sánchez, Alfonso,Illescas, Beatriz M.,Rojo, Javier,Martín, Nazario
, p. 10544 - 10546 (2016)
The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields. This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications.
