108695-41-6

Basic information

• Product Name: Benzene, 1,4-dimethoxy-2-(2-methyl-2-cyclopropen-1-yl)-
• CAS NO: 108695-41-6
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 108695-41-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-dimethoxy-2-(2-methyl-2-cyclopropen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-dimethoxy-2-(2-methyl-2-cyclopropen-1-yl)-(108695-41-6)
• EPA Substance Registry System: Benzene, 1,4-dimethoxy-2-(2-methyl-2-cyclopropen-1-yl)-(108695-41-6)

Safety Data

• Hazardous Substances Data: 108695-41-6(Hazardous Substances Data)

Upstream product

• 160835-14-3 trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one tosylhydrazone 
• 118709-30-1 trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one 

Relevant articles and documents

Metal-catalyzed cyclopropene rearrangements for benzannulation: Evaluation of an anthraquinone synthesis pathway and reevaluation of the parallel approach via carbene-chromium complexes

The reaction of 3-arylcyclopropenes with Cr(CO)6 and Mo(CO)6 produces naphthols, in an example of metal-promoted benzannulation. Substituents at C- 3 (in addition to aryl) have a strong effect on the success of the process: 3-H deriv