108734-36-7Relevant articles and documents
Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling
Cao, Qun,Howard, Joseph L.,Wheatley, Emilie,Browne, Duncan L.
supporting information, p. 11339 - 11343 (2018/08/28)
A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross-coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both C(sp3)–C(sp2) and C(sp2)–C(sp2) couplings and is tolerant to many important functional groups. The method may offer broad reaching opportunities for the in situ generation organometallic compounds from base metals and their concomitant engagement in synthetic reactions via mechanochemical methods.
SYNTHETIC STUDIES OF RABDOSIA DITERPENE LACTONES I: THE PREPARATION OF A KEY TRICYCLIC INTERMEDIATE
Kenny, Martin J.,Mander, Lewis N.,Sethi, S. Paul
, p. 3923 - 3926 (2007/10/02)
A strategy is proposed for the synthesis of Rabdosia diterpene lactones, eg. effusin 2 and the preparation of a suitable tricyclic intermediate 6 described.