109057-51-4

Basic information

• Product Name: Se-phenyl hexaneselenoate
• Synonyms: Se-phenyl hexaneselenoate
• CAS NO: 109057-51-4
• Molecular Weight: 255.218
• Mol File: 109057-51-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Se-phenyl hexaneselenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Se-phenyl hexaneselenoate(109057-51-4)
• EPA Substance Registry System: Se-phenyl hexaneselenoate(109057-51-4)

Safety Data

• Hazardous Substances Data: 109057-51-4(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 142-61-0 Hexanoyl chloride 
• 165278-85-3 (Z)-1-(phenylseleno)-1-hexen-1-yl p-toluenesulfonate 
• 114953-80-9 2,2,2-trifluoro-1-(phenylselanyl)ethanol 
• 1092379-00-4 C₁₀H₇F₇OSe 
• 1092378-99-8 2,2,3,3,3-pentafluoro-1-(phenylselanyl)propanol 
• 84993-35-1 1-Phenylselenenylmethylcyclohexene 
• 14370-82-2 allyl phenyl selenide 
• 68001-64-9 (hex-1-ynyl)(phenyl)selane 
• 33861-17-5 phenyl trimethylsilyl selenide 
• 109057-53-6 (Cyclohex-1-enyl-phenylselanyl-methyl)-trimethyl-silane 
• 109057-45-6 Trimethyl-(1-phenylselanyl-allyl)-silane 
• 108-86-1 bromobenzene 
• 1119-67-1 1-iodo-1-hexyne 

Relevant articles and documents

The Synthesis of Se-Alkyl Alkaneselenoates via (1-Iodo-1-alkenyl)dialkylboranes

Se-Alkyl alkaneselenoates were formed in moderate to good yields by successive reactions of (1-iodo-1-alkenyl)bis(1,2-dimethylpropyl)boranes with alkylselenomagnesium bromides and alkaline hydrogen peroxide.

1-(organoselanyl)perfluoroalkanols: A stable and efficient precursor for organoselenols

The 1-(organoselanyl)perfluoroalkanols 1, 3, 4, and 10 were successfully prepared and reactions with hexanoyl chlorides to produce the corresponding esters 5, 7, and 8, accompanied by the selenoesters 6 were conducted. The DBU-mediated alkylations of the heptafluorobutanols 4, 10, and the α-p-nitro-benzoate 2 with alkyl halides easily provided alkyl phenyl selenides 9a-9i and 11a-11c in good to high yields. Copyright

Synthesis of substituted Se-phenyl selenocarboxylates from terminal alkynes

Se-Phenyl selenocarboxylates have been conveniently prepared from (phenylseleno)acetylenes by treatment with p-toluenesulfonic acid monohydrate in dichloromethane. This easy conversion is compatible with a broad range of oxygen- and nitrogen-containing functional groups. The Se-phenyl selenocarboxylates were easily converted into the corresponding esters and amides. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Cleavage of Se-Se bond by Sm/cat. Cocl2 system: A novel method for the synthesis of selenoesters

The Sm/cat. COCl2 system promoted desalinates to react with anhydrides or acyl chlorides to afford selenoesters in good yield under mild and neutral conditions.