109179-39-7Relevant articles and documents
CeCl3/Sm system induced reductive cleavage of the Se-Se bond in diaryl diselenides: A novel method for the synthesis of β-selenoesters and β-selenonitriles
Li, Xue,Zhang, Songlin,Wang, Yulu,Zhang, Yongmin
, p. 1111 - 1113 (2002)
The Se-Se bond in diselenides was reduced by CeCl3/Sm system to produce selenolate anions, which react with α,β-unsaturated esters or α,β-unsaturated nitriles to afford β-selenoesters and β-selenonitriles, respectively.
β-Cyclodextrin-promoted addition of benzeneselenol to conjugated alkenes in water
Srinivas, Boga,Kumar, Vydyula Pavan,Sridhar, Regati,Reddy, Vutukuri Prakash,Nageswar, Yadavalli Venkata Durga,Rao, Kakulapati Rama
experimental part, p. 1080 - 1084 (2009/10/17)
For the first time, a mild and efficient procedure was developed for the conjugate addition of α,β-unsaturated compounds to benzeneselenol providing β-(phenylseleno)-substituted compounds (Scheme). The reaction was promoted by β-cyclodextrin, proceeded in
Convenient preparation of benzylseleno- and phenylselenoalkanoic acids: Reagents for synthesis of organoselenium compounds
Bhalla, Aman,Sharma, Sitansh,Bhasin, Kuldip K.,Bari, Shamsher S.
, p. 783 - 793 (2007/10/03)
An efficient and operationally simple route to benzylseleno- and phenylselenoalkanoic acids from ethyl benzyl/phenylselenoalkanoates is described. This involves preparation of ethyl benzyl/phenylselenoalkanoates as substrates by reaction of dibenzyl/diphenyl diselenide and sodium borohydride with ethyl chloroalkanoates in ethanol followed by basic hydrolysis and subsequent acidification. Copyright Taylor & Francis Group, LLC.
