109183-33-7

Basic information

• Product Name: (1R*,2S*)-2-phenyl-11-oxabicyclo<8.3.0>tridec-9-en-4-one
• CAS NO: 109183-33-7
• Molecular Weight: 270.371
• Mol File: 109183-33-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R*,2S*)-2-phenyl-11-oxabicyclo<8.3.0>tridec-9-en-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R*,2S*)-2-phenyl-11-oxabicyclo<8.3.0>tridec-9-en-4-one(109183-33-7)
• EPA Substance Registry System: (1R*,2S*)-2-phenyl-11-oxabicyclo<8.3.0>tridec-9-en-4-one(109183-33-7)

Safety Data

• Hazardous Substances Data: 109183-33-7(Hazardous Substances Data)

Upstream product

• 80893-84-1 1,7-bis(trimethylsiloxy)bicyclo[5.1.0]octane 
• 93652-37-0 4-phenyl-3-butenyl para-toluenesulfonate 
• 935-29-5 1,3-cyclooctanedione 
• 2050-20-6 diethyl pimelate 
• 19719-90-5 1,2-Bis-(trimethylsiloxy)-cyclohepten-⁽¹⁾ 
• 108176-31-4 3-<((E)-4-phenyl-3-butenyl)oxy>-2-cycloocten-1-one 

Relevant articles and documents

Mechanism of Intramolecular Photocycloadditions of Cyclooctenones

The intramolecular photochemical cycloadditions of a number of 4'-substituted (3'-butenyloxy)-cyclooctenones have been studied.Two classes of substrates were found.One class (phenyl- and vinyl-substituted) forms adducts in an efficient reaction, while the rest of the compounds from photoproducts slowly and in low yield.The behavior of a carbon analogue shows that rotational relaxation of the cyclooctenone triplet is faster than cycloaddition.Based on quenching and sensitization studies, it has been suggested that the substituent effect is indicative of an enhanced rate of cyclization to form a 1,4-biradical.