109395-50-8

Basic information

• Product Name: Benzothiazole, 2-methyl-5-(2,4,6-trimethylphenyl)-
• CAS NO: 109395-50-8
• Molecular Formula: C17H17NS
• Molecular Weight: 267.395
• Mol File: 109395-50-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzothiazole, 2-methyl-5-(2,4,6-trimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 2-methyl-5-(2,4,6-trimethylphenyl)-(109395-50-8)
• EPA Substance Registry System: Benzothiazole, 2-methyl-5-(2,4,6-trimethylphenyl)-(109395-50-8)

Safety Data

• Hazardous Substances Data: 109395-50-8(Hazardous Substances Data)

Upstream product

• 76209-05-7 4,4′-dibromo-2,2′-dinitrodiphenyl disulfide 
• 3460-18-2 1,4-dibromo-2-nitrobenzene 
• 63837-11-6 5-bromo-2-methylbenzothiazole 
• 1077-62-9 SnMe₃(C₆H₂Me₃-2,4,6) 
• 94216-91-8 5-(3,3-dimethyl-triaz-1-enyl)-2-methyl-benzothiazole 
• 108-67-8 1,3,5-trimethyl-benzene 

Relevant articles and documents

Synthesis of 5- and 6-Substituted 2-Methylbenzothiazoles under Conditions of Metal Complex Catalysis

Methods are proposed for preparation of 5- and 6-substituted 2-methylbenzothiazoles by reactions of organozinc and organotin compounds with 5- and 6-bromo-2-methylbenzothiazoles, catalyzed by palladium complexes. The reactions of organozinc compounds with 5(6)-bromo-2-methylbenzothiazoles occur in THF at 20°C in the presence of PdCl2(dppf), and those of organotin compounds are carried out in DMF, aqueous DMF, or water at 40-100°C in the presence of PdCl2, Pd(OAc)2, or PdCl2(PPh3)2.