1094598-64-7

Basic information

• Product Name: 3-(3-{[1-phenyl-meth-(E)-ylidene]-amino}-propyl)-1-propyl-3H-imidazol-1-ium bromide
• Synonyms: 3-(3-{[1-phenyl-meth-(E)-ylidene]-amino}-propyl)-1-propyl-3H-imidazol-1-ium bromide
• CAS NO: 1094598-64-7
• Molecular Weight: 336.275
• Mol File: 1094598-64-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(3-{[1-phenyl-meth-(E)-ylidene]-amino}-propyl)-1-propyl-3H-imidazol-1-ium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-{[1-phenyl-meth-(E)-ylidene]-amino}-propyl)-1-propyl-3H-imidazol-1-ium bromide(1094598-64-7)
• EPA Substance Registry System: 3-(3-{[1-phenyl-meth-(E)-ylidene]-amino}-propyl)-1-propyl-3H-imidazol-1-ium bromide(1094598-64-7)

Safety Data

• Hazardous Substances Data: 1094598-64-7(Hazardous Substances Data)

Upstream product

• 35203-44-2 1-propyl-1H-imidazole 
• 1026774-20-8 (3-bromo-propyl)-[1-phenyl-meth-(E)-ylidene]-amine 

Downstream Products

• 1094598-68-1 (Z)-9-phenyl-1-propyl-5,6,7,8-tetrahydro-1H-imidazo[1,2-a][1,4]diazepine 

Relevant articles and documents

Addition of N-heterocyclic carbenes to imines: phenoxide assisted deprotonation of an imidazolium moiety and generation of Breslow intermediates derived from imines

Reactions between imidazolium-imine salts and base result in C-C bond formation via intermediate N-heterocyclic carbenes. In the presence of a proximal OH moiety, carbene formation occurs via intramolecular deprotonation by phenoxide. For simple imines, a reactive Breslow-type intermediate gives access to new heterocycles with the formation of six-and seven-member rings.