1095572-68-1

Basic information

• Product Name: Pt(CH₃C₆H₄)(ClC₆H₃CHNCH₂(ClC₆H₄))S(C₂H₅)2
• CAS NO: 1095572-68-1
• Molecular Weight: 639.548
• Mol File: 1095572-68-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(CH₃C₆H₄)(ClC₆H₃CHNCH₂(ClC₆H₄))S(C₂H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(CH₃C₆H₄)(ClC₆H₃CHNCH₂(ClC₆H₄))S(C₂H₅)2(1095572-68-1)
• EPA Substance Registry System: Pt(CH₃C₆H₄)(ClC₆H₃CHNCH₂(ClC₆H₄))S(C₂H₅)2(1095572-68-1)

Safety Data

• Hazardous Substances Data: 1095572-68-1(Hazardous Substances Data)

Upstream product

• 64827-19-6 bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)] 
• 31264-06-9 N-(4-chlorobenzylidene)-4-chlorobenzylamine 

Downstream Products

• 1095572-84-1 Pt(CH₃C₆H₄)(ClC₆H₃CHNCH₂(ClC₆H₄))P(C₆H₅)3 

Relevant articles and documents

Five- and Seven-membered metallacycles in [C,N,N′] and [C,N] Cycloplatinated Compounds

The reactions of cs-[Pt(4-C6H4Me)2(μ- SEt2)]2 with ligands ArCH=NCH2CH 2NMe2 (Ar = 4-CIC6H4 (la); 2-BrC 6H4 (lb); 2,6-Cl2C6H3 (1c); C6F5 (1d)) and ArCH=NCH2(4-ClC 6H4) (Ar = 4-ClC6H4 (1e); 2-BrC 6H4 (If); 2,6-Cl2C6H3 (1g); C6F5 (1h)) were studied. Several types of compounds were formed including (i) [N,N'] coordination compounds (2a, 2c, 2d), (ii) [C,N,N'] platinum(IV) (3b, 3c), [C,N,N'] platinum(II) (4a), and [C,N] platinum(Π) (4e) cyclometalated compounds with a five-membered metallacycle, and (iii) [C,N,N'] platinum(Π) (5c) and [C,N] platinum(Π) (5f, 5g) cyclometalated compounds with a seven-membered metallacycle. The reactions of the obtained cyclometalated compounds with triphenylphosphine were studied, and the new compounds were fully characterized including structure determinations for 4a, 5c, 5g, and the phosphine derivative 7 g'. The ease of formation of seven-membered metallacycles is discussed on the basis of the structure of the ligand (terdentate versus bidentate) and the C-X bond to be activated.