109640-15-5Relevant articles and documents
Diastereo- And Enantioselective Synthesis of Structurally Diverse Succinate, Butyrolactone, and Trifluoromethyl Derivatives by Iridium-Catalyzed Hydrogenation of Tetrasubstituted Olefins
Kerdphon, Sutthichat,Ponra, Sudipta,Yang, Jianping,Wu, Haibo,Eriksson, Lars,Andersson, Pher G.
, p. 6169 - 6176 (2019/07/03)
A highly efficient iridium N,P-ligand-catalyzed asymmetric hydrogenation of functionalized tetrasubstituted olefins lacking a directing group has been developed. Various structural diverse chiral succinate derivatives were obtained in high yields and exce
Catalytic hydrogenation of α,β-unsaturated carboxylic acid derivatives using copper(i)/N-heterocyclic carbene complexes
Zimmermann, Birte M.,Kobosil, Sarah C. K.,Teichert, Johannes F.
supporting information, p. 2293 - 2296 (2019/02/27)
A simple and air-stable copper(i)/N-heterocyclic carbene complex enables the catalytic hydrogenation of enoates and enamides, hitherto unreactive substrates employing homogeneous copper catalysis and H2 as a terminal reducing agent. This atom economic transformation replaces commonly employed hydrosilanes and can also be carried out in an asymmetric fashion.
Stereoselective Hydrogen Transfer Reactions Involving Acyclic Radicals. Tandem Substituted Tetrahydrofuran Formation and Stereoselective Reduction: Synthesis of the C17-C22 Subunit of Ionomycin
Guindon, Y.,Yoakim, C.,Gorys, V.,Ogilvie, W. W.,Delorme, D.,et al.
, p. 1166 - 1178 (2007/10/02)
The tandem iodoetherification reaction and stereoselective reduction of acyclic redicals has been used in the stereocontrolled synthesis of substituted tetrahydrofurans.Such a tetrahydrofuran intermediate is regioselectively cleaved using Me2BBr to reveal
