1096704-50-5

Basic information

• Product Name: 4-methyl-3-(adamantyl)-2-(OH)-C6H4C=N(2’-(2’’-(OMe)-C6H4)C6H4)
• Synonyms: 4-methyl-3-(adamantyl)-2-(OH)-C6H4C=N(2’-(2’’-(OMe)-C6H4)C6H4)
• CAS NO: 1096704-50-5
• Molecular Weight: 451.609
• Mol File: 1096704-50-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-methyl-3-(adamantyl)-2-(OH)-C6H4C=N(2’-(2’’-(OMe)-C6H4)C6H4)(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-3-(adamantyl)-2-(OH)-C6H4C=N(2’-(2’’-(OMe)-C6H4)C6H4)(1096704-50-5)
• EPA Substance Registry System: 4-methyl-3-(adamantyl)-2-(OH)-C6H4C=N(2’-(2’’-(OMe)-C6H4)C6H4)(1096704-50-5)

Safety Data

• Hazardous Substances Data: 1096704-50-5(Hazardous Substances Data)

Upstream product

• 615-36-1 2-bromoaniline 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 1206-76-4 2-(2'-methoxyphenyl)aniline 
• 231963-91-0 3-(adamantan-1-yl)-2-hydroxy-5-methylbenzaldehyde 

Downstream Products

• 1096704-51-6 C₃₁H₃₂Cl₃NO₂Ti 

Relevant articles and documents

TRANSITION METAL COMPOUND, CATALYST FOR OLEFIN MULTIMERIZATION AND METHOD FOR PRODUCING OLEFIN MULTIMER

PROBLEM TO BE SOLVED: To provide a novel transition metal compound, a catalyst for olefin multimerization containing the compound and having excellent activity and selectivity, and a method for producing an olefin multimer that is performed in the presence of the catalyst for olefin multimerization. SOLUTION: The present invention provides a transition metal compound of general formula (1), a catalyst for olefin polymerization containing the same, and a method for producing an olefin polymer with the catalyst (R1-R6 are a hydrogen atom or the like, M is a transition metal atom in the periodic table group 6, n is a valence of M, X is a halogen atom or the like, Y is an oxygen atom or the like, Z is a hydrocarbon group or the like). SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT

Highly selective olefin trimerization catalysis by a borane-activated titanium trimethyl complex

Reaction of a trimethyl titanium complex, (FI)TiMe3 (FI = phenoxy-imine), with 1 equiv of B(C6F5)3 gives [(FI)TiMe2][MeB(C6F5)3], an effective precatalyst for the selective trimerization of ethylene. Mechanistic studies indicate that catalyst initiation involves generation of an active TiII species by olefin insertion into a Ti-Me bond, followed by β-H elimination and reductive elimination of methane, and that initiation is slow relative to trimerization. (FI)TiMe3/B(C6F 5)3 also leads to a competent catalyst for the oligomerization of α-olefins, displaying high selectivity for trimers (>95%), approximately 85% of which are one regioisomer. This catalyst system thus shows promise for selectively converting light α-olefins into transportation fuels and lubricants.