109685-07-6

Basic information

• Product Name: 2-deuterio-4-hydroxy-3-methoxybenzyl alcohol
• Synonyms: 2-deuterio-4-hydroxy-3-methoxybenzyl alcohol
• CAS NO: 109685-07-6
• Molecular Weight: 155.158
• Mol File: 109685-07-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-deuterio-4-hydroxy-3-methoxybenzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-deuterio-4-hydroxy-3-methoxybenzyl alcohol(109685-07-6)
• EPA Substance Registry System: 2-deuterio-4-hydroxy-3-methoxybenzyl alcohol(109685-07-6)

Safety Data

• Hazardous Substances Data: 109685-07-6(Hazardous Substances Data)

Upstream product

• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 
• 109685-12-3 C₉H₁₁⁽²⁾HO₃ 

Downstream Products

• 109685-10-1 3-deuterio-2-methoxy-1,4-benzoquinone 

Relevant articles and documents

Metalation of Phenols. Synthesis of Benzoquinones by the Oxidative Degradation Approach

In a effort to explore the potential of so-called oxidative degradation approach for the synthesis of quinones, we have investigated the direct metalation of a number of simple phenols such as o- and p-hydroxybenzyl alcohols, benzyl methyl ethers and N,N-dimethylbenzylamines.Apparently, only those phenolic substrates having available both a coordinating group for chelation and an electron-withdrawing group in a 1,3-relationship are efficiently lithiated, by the action of n-BuLi, in a regioselective manner.Those positions on the aromatic nucleus just flanked by a coordinating, or an acid-base, group could be metalated by action of the t-BuLi/THP system, in favorable cases.