109687-59-4

Basic information

• Product Name: Benzene, 1-(phenylmethoxy)-4-[2-(phenylseleno)-3-butenyl]-
• CAS NO: 109687-59-4
• Molecular Formula: C23H22OSe
• Molecular Weight: 393.387
• Mol File: 109687-59-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(phenylmethoxy)-4-[2-(phenylseleno)-3-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(phenylmethoxy)-4-[2-(phenylseleno)-3-butenyl]-(109687-59-4)
• EPA Substance Registry System: Benzene, 1-(phenylmethoxy)-4-[2-(phenylseleno)-3-butenyl]-(109687-59-4)

Safety Data

• Hazardous Substances Data: 109687-59-4(Hazardous Substances Data)

Upstream product

• 14370-82-2 allyl phenyl selenide 
• 5544-60-5 4-(benzyloxy)benzyl bromide 

Downstream Products

• 109687-62-9 2-<(tert-butoxycarbonyl)amino>-1-<4-(phenylmethoxy)-phenyl>-6-<(2-tetrahydropyranyl)oxy>-trans-3-hexene 
• 109687-61-8 4-(phenylseleno)-1-<4-(phenylmethoxy)phenyl>-6-<(2-tetrahydropyranyl)oxy>-trans-2-hexene 
• 126410-76-2 (E)-7-(4-Benzyloxy-phenyl)-6-tert-butoxycarbonylamino-hept-4-enoic acid 
• 126410-77-3 [(E)-1-(4-Benzyloxy-benzyl)-6-hydroxy-hex-2-enyl]-carbamic acid tert-butyl ester 
• 109687-60-7 1-(phenylseleno)-4-<(4-phenylmetoxy)phenyl>-trans-2-butene 

Relevant articles and documents

New Approaches to the Synthesis of trans-Alkene Isosteres of Dipeptides

Two new syntheses of protected dipeptide analogues bearing a trans carbon-carbon double bond in place of the amide linkage are reported.One route is a linear synthesis employing the rearrangement of an allylic selenide to a protected allylic amine.The second route is convergent and uses the Julia olefin synthesis in a key step.The latter route is fully stereocontrolled and has been used to prepare protected trans-alkene isosteres of the dipeptides TyrAla, PhePhe, LeuPhe, and LeuLeu.