109705-27-3Relevant articles and documents
Electrochemical fluorination and radiofluorination of methyl(phenylthio)acetate using tetrabutylammonium fluoride (TBAF)
Balandeh, Mehrdad,Waldmann, Christopher,Shirazi, Daniela,Gomez, Adrian,Rios, Alejandra,Allison, Nathanael,Khan, Asad,Sadeghi, Saman
, p. G99 - G103 (2017)
Electrochemical fluorination of methyl(phenylthio)acetate was achieved using tetrabutylammonium fluoride (TBAF). Electrochemical fluorination was performed under potentiostatic anodic oxidation using an undivided cell in acetonitrile containing TBAF and t
ELECTROCHEMICAL FLASH FLUORINATION AND RADIOFLUORINATION
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Page/Page column 0202; 0205-0209, (2019/08/26)
Provided herein are methods of fluorinating organic compounds. The electrochemical fluorination and radiofluorination of organic molecules using the cation pool technique is described, where the 18F and/or 19F-fluorine ions are added after the process of
Effect of solvents on the selective electrofluorination of aromatic compounds containing active methylene groups
Suryanarayanan, V.,Noel, M.
, p. 177 - 180 (2007/10/03)
Voltammetry and constant current electrolysis was used to study the oxidative fluorination of PhSCH2COOMe, PhSCH2CONH2, PhSCH2COOPh and PhCH2CN in solvent-free and Et3N*3HF and Et3N*3HF dissolved in CH3CN, THF, DME and sulfolane. Sulfolane, DME and THF containig Et3N*3HF show much lower oxidation limits when compared to CH3CN/Et3N*3HF. These compounds udergo simultaneous oxidation along with background oxidation processes. Solvent-free Et3N*3HF has a much wider anodic potential range for the oxidation of organic compounds. Selective electrofluorination of PhSCH2COOPh does not show significant solvent effects. THF and DME were found to be more efficient for the selective fluorination of PhSCH2CONH2 and PhCH2CN compared to CH3CN. - Keywords: Selective electrofluorination; Active methylene compounds; Solvent effects
