109772-87-4

Basic information

• Product Name: Benzeneacetonitrile, 2-nitro-a-(phenylamino)-
• CAS NO: 109772-87-4
• Molecular Formula: C14H11N3O2
• Molecular Weight: 253.26
• Mol File: 109772-87-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzeneacetonitrile, 2-nitro-a-(phenylamino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, 2-nitro-a-(phenylamino)-(109772-87-4)
• EPA Substance Registry System: Benzeneacetonitrile, 2-nitro-a-(phenylamino)-(109772-87-4)

Safety Data

• Hazardous Substances Data: 109772-87-4(Hazardous Substances Data)

Upstream product

• 151-50-8 potassium cyanide 
• 62-53-3 aniline 
• 552-89-6 2-nitro-benzaldehyde 
• 17064-77-6 N-(2-nitrobenzylidene)aniline 
• 7677-24-9 trimethylsilyl cyanide 
• 99-61-6 3-nitro-benzaldehyde 

Downstream Products

• 109772-94-3 3-cyano-2-phenyl-2H-indazole 1-oxide 
• 17049-65-9 2-phenyl-1,2-dihydro-3H-indazol-3-one 
• 861326-09-2 sulfurous acid mono-(1-oxy-2-phenyl-2H-indazol-3-yl ester) 

Relevant articles and documents

Catalytic Strecker reaction: g-C3N4-anchored sulfonic acid organocatalyst for the synthesis of α-aminonitriles

Abstract: Efficient organocatalyst for enantioselective Strecker reaction was synthesized using g-C3N4 sheets (CN). CN-anchored sulfonic acid (CN-Bu-SO3H) was found to be a highly efficient and recoverable organocatalyst f

Cu/Ni-doped sulfated zirconium oxide immobilized on CdFe2O4 NPs: a cheap, sustainable and magnetically recyclable inorgano-catalyst for the efficient preparation of α-aminonitriles in aqueous media

Abstract: A new multifunctional bimetallic nanocatalyst was prepared by immobilization of Cu/Ni-doped sulfated zirconium oxide on magnetic cadmium ferrite (CdFe2O4@SiO2@ZrO2/SO42?/Cu/Ni) and used as an efficient recyclable catalyst for one-pot as well as stepwise preparation of α-aminonitriles under mild conditions. The magnetic nanocatalyst was characterized by FTIR, TGA, VSM, XRD, EDX, FE-SEM, and TEM analyses. Also, the surface acidity of the catalyst was measured by pyridine adsorption assay. The catalyst possesses various active sites which could catalyst a variety of aromatic and aliphatic aldehydes to the corresponding α-amionitriles under moderate to high yields in the presence of aniline. Furthermore, transformation of ketones to the desired α-amionitriles and some bis-aminonitriles was also performed by this method. The catalyst could be readily recovered from the reaction mixture and reused for several times without significant loss of activity. Graphic abstract: A general and efficient method has been developed for transformation of a variety of aliphatic, aromatic aldehydes and ketones to the corresponding α-aminonitriles using a multifunctional recyclable CdFe2O4@SiO2@ZrO2/SO42?/Cu/Ni nanocatalyst.[Figure not available: see fulltext.]

Gallic acid grafted to amine-functionalized magnetic nanoparticles as a proficient catalyst for environmentally friendly synthesis of α-aminonitriles

An effective approach of one-pot catalytic Strecker reaction between aromatic aldehydes, aniline or toluidine and trimethylsilyl cyanide in the presence of amine-functionalized Fe3O4@SiO2 nanoparticles grafted with gallic