109853-36-3

Basic information

• Product Name: ((1R,2R,3S,4S)-3-p-Tolylcarbamoyl-bicyclo[2.2.1]hept-5-en-2-yl)-carbamic acid benzyl ester
• Synonyms: ((1R,2R,3S,4S)-3-p-Tolylcarbamoyl-bicyclo[2.2.1]hept-5-en-2-yl)-carbamic acid benzyl ester
• CAS NO: 109853-36-3
• Molecular Weight: 376.455
• Mol File: 109853-36-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((1R,2R,3S,4S)-3-p-Tolylcarbamoyl-bicyclo[2.2.1]hept-5-en-2-yl)-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ((1R,2R,3S,4S)-3-p-Tolylcarbamoyl-bicyclo[2.2.1]hept-5-en-2-yl)-carbamic acid benzyl ester(109853-36-3)
• EPA Substance Registry System: ((1R,2R,3S,4S)-3-p-Tolylcarbamoyl-bicyclo[2.2.1]hept-5-en-2-yl)-carbamic acid benzyl ester(109853-36-3)

Safety Data

• Hazardous Substances Data: 109853-36-3(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 109853-34-1 3-exo-benzyloxycarbonylaminobicyclo<2.2.1>hept-5-ene-2-exo-carboxylic acid 
• 92511-32-5 3-exo-aminobicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 109853-49-8 (1S,2S,3R,4R)-3-Amino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid p-tolylamide; hydrobromide 

Relevant articles and documents

Stereochemical Studies. Part 103. Saturated Heterocycles. Part 107. Preparation of 3-Mono and 2,3-Di-substituted Pyrimidin-4(3H)-ones in Retro-Diels-Alder Reactions. The Correct 1,2-Disubstituted Structure of the Compounds previously described as 2,3-Disu

The orthofomate cyclization of carboxamides (4) obtained from 3-exo-aminobicyclohept-5-ene-2-exo-carboxylic acid (1) yielded intermediate 8,9,10-trinorbornene-fused pyrimidinones (5) and hence 3-substituted pyrimidin-4(3H)-ones (6) through the spli