109899-66-3

Basic information

• Product Name: (4-bromo-phenyl)-(5-nitro-[2]pyridyl)-amine
• Synonyms: (4-bromo-phenyl)-(5-nitro-[2]pyridyl)-amine;N-(4-bromophenyl)-5-nitropyridin-2-amine
• CAS NO: 109899-66-3
• Molecular Formula: C₁₁H₈BrN₃O₂
• Molecular Weight: 294
• Mol File: 109899-66-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (4-bromo-phenyl)-(5-nitro-[2]pyridyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-bromo-phenyl)-(5-nitro-[2]pyridyl)-amine(109899-66-3)
• EPA Substance Registry System: (4-bromo-phenyl)-(5-nitro-[2]pyridyl)-amine(109899-66-3)

Safety Data

• Hazardous Substances Data: 109899-66-3(Hazardous Substances Data)

Upstream product

• 4548-45-2 2-chloro-5-nitropyridine 
• 106-40-1 4-bromo-aniline 
• 2530-26-9 3-nitropyridine 

Relevant articles and documents

S NH Arylamination of 3-Nitropyridine: A Competitive Formation of 2-Arylamino-5-nitropyridines and 2-Arylamino-5-nitrosopyridines

Arylamination of 3-nitropyridine via the nucleophilic substitution of hydrogen leads to a mixture of 2-arylamino-5-nitropyridines and novel 2-arylamino-5-nitrosopyridines, with the latter as the major product. The proposed mechanism includes the formation of σ H -adducts and their further aromatization proceeding either through an oxidative pathway or intramolecular Red/Ox pathway of the S NH reaction. Moreover, we have shown that nitroso compounds can be selectively oxidized with m -chloroperbenzoic acid to give the corresponding nitro derivatives or their N -oxides, depending on the reaction temperature and the amount of oxidant.