109926-14-9

Basic information

• Product Name: diethyl 2-bromo-2-benzylmalonate
• Synonyms: diethyl 2-bromo-2-benzylmalonate
• CAS NO: 109926-14-9
• Molecular Weight: 329.191
• Mol File: 109926-14-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diethyl 2-bromo-2-benzylmalonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-bromo-2-benzylmalonate(109926-14-9)
• EPA Substance Registry System: diethyl 2-bromo-2-benzylmalonate(109926-14-9)

Safety Data

• Hazardous Substances Data: 109926-14-9(Hazardous Substances Data)

Upstream product

• 685-87-0 Diethyl 2-bromomalonate 
• 620-05-3 iodomethylbenzene 
• 607-81-8 diethyl 2-benzylmalonate 

Downstream Products

• 141344-93-6 2,2-Bis(ethoxycarbonyl)-4-phenyl-1,2-dihydronaphthalene 

Relevant articles and documents

Conversion of nucleophilic halides to electrophilic halides: Efficient and selective halogenation of azinones, amides, and carbonyl compounds using metal halide/lead tetraacetate

AlCl3/Pb(OAc)4 and ZnBr2/Pb(OAc) 4 are efficient electrophilic N- and α-C-halogenating agents. A variety of azinones, amides and carbonyl compounds were chemoselectively and regioselectively N-, or α-C-halogenated in good to excellent yield using AlCl3/Pb(OAc)4 and ZnBr2/Pb(OAc)4 in acetonitrile. Georg Thieme Verlag Stuttgart.

Green molecular transformation by a B12-TiO2 hybrid catalyst as an alternative to tributyltin hydride

The B12-TiO2 hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.