109928-28-1

Basic information

• Product Name: 3‐methyl‐1,1‐diphenyl‐2,3‐dihydro‐1H‐silole
• Synonyms: 3‐methyl‐1,1‐diphenyl‐2,3‐dihydro‐1H‐silole
• CAS NO: 109928-28-1
• Molecular Weight: 250.415
• Mol File: 109928-28-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3‐methyl‐1,1‐diphenyl‐2,3‐dihydro‐1H‐silole(CAS DataBase Reference)
• NIST Chemistry Reference: 3‐methyl‐1,1‐diphenyl‐2,3‐dihydro‐1H‐silole(109928-28-1)
• EPA Substance Registry System: 3‐methyl‐1,1‐diphenyl‐2,3‐dihydro‐1H‐silole(109928-28-1)

Safety Data

• Hazardous Substances Data: 109928-28-1(Hazardous Substances Data)

Upstream product

• 775-12-2 diphenylsilane 
• 34106-93-9 1,1-diphenylsilacyclopent-3-ene 
• 74-88-4 methyl iodide 
• 74-83-9 methyl bromide 

Relevant articles and documents

Nickel-catalyzed insertions of vinylidenes into Si-H bonds

A nickel-catalyzed reductive cyclization of 1,1-dichloroalkenyl silanes is reported. The products of this reaction are unsaturated five-or six-membered silacycles. Intermolecular variants are also described, providing access to trisubstituted vinyl silanes that are not accessible by alkyne hydrosilylation or sila-Heck-type processes. A variety of silanes can be utilized, including those that serve as nucleophilic partners in Hiyama cross-coupling reactions. Mechanistic studies using deuterium-labelled silanes are described. This journal is