110063-95-1

Basic information

• Product Name: Silanamine, 1-chloro-N-phenyl-1,1-dipropoxy-
• CAS NO: 110063-95-1
• Molecular Formula: C12H20ClNO2Si
• Molecular Weight: 273.835
• Mol File: 110063-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silanamine, 1-chloro-N-phenyl-1,1-dipropoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1-chloro-N-phenyl-1,1-dipropoxy-(110063-95-1)
• EPA Substance Registry System: Silanamine, 1-chloro-N-phenyl-1,1-dipropoxy-(110063-95-1)

Safety Data

• Hazardous Substances Data: 110063-95-1(Hazardous Substances Data)

Upstream product

• 18141-43-0 dichloro-di-n-propoxy-silane 
• 62-53-3 aniline 

Relevant articles and documents

Coordination Compounds of Organometallic Bases of Group IV Elements: Part X - Reactions of 1-Chloro-1,1-diethoxy/di-n-propoxy-N-(phenyl/o-chlorophenyl/p-methylphenyl/n-butyl)silanamines with Tin(IV) and Titanium(IV) Chlorides at -10 deg C

The reactions of the title ligands with tin(IV) and titanium(IV) chlorides at -10 deg in petroleum ether (40-60 deg C) in 1:1 molar ratio give complexes of rearranged silanamines as evidenced by IR and PMR spectral data as well as base exchange reactions.Whereas, 1-chloro-1,1-diethoxy/di-n-propoxy-N-(phenyl/o-chlorophenyl)silanamines afford complexes of composition RSi(NHR')3.2MCl4, those obtained from 1-chloro-1,1-diethoxy/di-n-propoxy-N-(p-methylphenyl/n-butyl)silanamines have the composition Si(NHR')4.3MCl4 (where R = OC2H5 or OC3H7-n; R' = C6H5, C6H4Cl(o), C6H4CH3(p) or C4H9(n); M = Ti or Sn).The formation of tetrakis(N-n-butyl/p-methylphenyl)silanamines is a novel observation.Further, filtrates from these reactions after keeping for 48 hr at room temperature invariably precipitate out complexes of the type R2Si(NHR')2.2MCl4 (ca. 20percent yield) as evidenced by their IR and PMR data.The isolation of these complexes may represent preferential displacement of chloro groups from original ligands as the initial reaction.