110118-60-0

Basic information

• Product Name: (η5-cyclopentadienyl)(η2-ethylene)hydrido(triphenylphosphine)iron
• CAS NO: 110118-60-0
• Molecular Weight: 412.294
• Mol File: 110118-60-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η5-cyclopentadienyl)(η2-ethylene)hydrido(triphenylphosphine)iron(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-cyclopentadienyl)(η2-ethylene)hydrido(triphenylphosphine)iron(110118-60-0)
• EPA Substance Registry System: (η5-cyclopentadienyl)(η2-ethylene)hydrido(triphenylphosphine)iron(110118-60-0)

Safety Data

• Hazardous Substances Data: 110118-60-0(Hazardous Substances Data)

Upstream product

• 19543-98-7 bis(triphenylphosphine)iron(II) chloride 
• 925-90-6 ethylmagnesium bromide 
• 16733-97-4 cyclopentadienyllithium 

Relevant articles and documents

Organyl Complexes of (ν5-Cyclopentadienyl)(triorganophosphano)iron

A series of organyliron complexes of the type Cp(L)2Fe-R (Cp = C5H5, C5H4Me, C5Me5; L = PhnMe3-nP, N = 0-3; R = Me, Et, Bu, Ph, CH2CH2Ph, CH=CH3) have been prepared either from the corresponding iron chlorides (1-7) and organomagnesium compounds or from Cp(COD)FeLi (8, 9), organic halide, and phosphane.The thermal stability of the ethyliron complexes 17 - 24 towards β-H elimination (to give the ν2-ethylene)iron hydrides 37 - 39 or the Cp(L)2FeH compounds 40 - 48) increases with the basicity of the phosphane ligand and decreases with increasing methyl-substitution of the Cp ligand.The vinyliron compounds 29 - 32, 54, and 55 react with ethylene with insertion into the vinyl-Fe bond to give the (ν3-crotyl)iron complexes 56 - 61 as the result of isomerization.The (ν1,ν2-alkenyl)iron compounds (62), C5Me5 (63) and (67) were isolated and are stable at 20 deg C.