1101906-42-6

Basic information

• Product Name: 4,4-dimethyl-2-(1,10-phenanthrolin-2-yl)-4,5-dihydrooxazole
• CAS NO: 1101906-42-6
• Molecular Weight: 277.326
• Mol File: 1101906-42-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4,4-dimethyl-2-(1,10-phenanthrolin-2-yl)-4,5-dihydrooxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4-dimethyl-2-(1,10-phenanthrolin-2-yl)-4,5-dihydrooxazole(1101906-42-6)
• EPA Substance Registry System: 4,4-dimethyl-2-(1,10-phenanthrolin-2-yl)-4,5-dihydrooxazole(1101906-42-6)

Safety Data

• Hazardous Substances Data: 1101906-42-6(Hazardous Substances Data)

Upstream product

• 124-68-5 2-Amino-2-methyl-1-propanol 
• 1082-19-5 1,10-phenanthroline-2-carbonitrile 
• 133435-90-2 2-methoxyimidate-1,10-phenanthroline 

Relevant articles and documents

Iron(II)-catalyzed intermolecular amino-oxygenation of olefins through the N - O bond cleavage of functionalized hydroxylamines

An iron-catalyzed diastereoselective intermolecular olefin amino-oxygenation reaction is reported, which proceeds via an iron-nitrenoid generated by the N - O bond cleavage of a functionalized hydroxylamine. In this reaction, a bench-stable hydroxylamine derivative is used as the amination reagent and oxidant. This method tolerates a range of synthetically valuable substrates that have been all incompatible with existing amino-oxygenation methods. It can also provide amino alcohol derivatives with regio- and stereochemical arrays complementary to known amino-oxygenation methods.

2-Oxazoline/benzoxazole-1,10-phenanthrolinylmetal (iron, cobalt or nickel) dichloride: Synthesis, characterization and their catalytic reactivity for the ethylene oligomerization

Series of 2-benzoxazole-1,10-phenanthrolines (L1-L4) and 2-oxazoline-1,10-phenanthrolines (L5-L8) were synthesized and used as tridentate N^N^N ligands in coordinating with metal (nickel, cobalt or iron) chlorides. Their metal complexes, nickel(II) (Ni1-Ni8), cobalt(II) (Co1-Co8) and iron(II) (Fe1-Fe8), were characterized by elemental and IR spectroscopic analyses. The molecular structures of the ligand L2 and the complexes Ni3, Co1, Co3 and Fe2 have been determined by the single-crystal crystallography. The nickel complex Ni3 and iron complex Fe2 display an octahedral geometry, whereas cobalt complex Co1 is with a distorted bipyramidal geometry and Co3 as square pyramidal geometry. At 10 atm ethylene, all the complexes showed good activities in ethylene dimerization upon activation with appropriate aluminum cocatalysts; the nickel complexes gave the activity up to 3.11 × 106 g mol-1(Ni) h-1 upon activation with diethylaluminum chloride (Et2AlCl), meanwhile the cobalt and iron complexes showed activities up to 1.51 × 106 g mol-1(Co) h-1 and 1.89 × 106 g mol-1(Fe) h-1, individually, upon activation with modified methylaluminoxane (MMAO).