110210-99-6Relevant articles and documents
REGIOSELECIVE HYDROXYSULPHENYLATION OF DERIVATIVES OF ALLYLIC ALCOHOLS AND AMINES
Samii, Zakaria K M Abd El,Ashmawy, Mohamed I Al,Mellor, John M
, p. 5289 - 5292 (1986)
Reaction of manganic acetate with diphenyldisulphide in dichloromethane-trifluoroacetic acid in the presence of allylic esters or amides of allylamine gives trifluoroacetoxysulphides and hence by ready hydrolysis vicinal hydroxysulphides.The regiochemical outcome can be controlled by selection of either an acetyl- or trifluoroacetyl derivative.