110211-35-3

Basic information

• Product Name: Silane, trimethyl(5-phenyl-1-pentynyl)-
• CAS NO: 110211-35-3
• Molecular Formula: C14H20Si
• Molecular Weight: 216.398
• Mol File: 110211-35-3.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(5-phenyl-1-pentynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(5-phenyl-1-pentynyl)-(110211-35-3)
• EPA Substance Registry System: Silane, trimethyl(5-phenyl-1-pentynyl)-(110211-35-3)

Safety Data

• Hazardous Substances Data: 110211-35-3(Hazardous Substances Data)

Upstream product

• 1823-14-9 5-phenyl-1-pentyne 
• 996-50-9 N,N-diethyl-1,1,1-trimethylsilanamine 
• 35761-91-2 5-iodo-1-trimethylsilyl-1-pentyne 
• 1078-58-6 diphenylzinc 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 637-59-2 1-Bromo-3-phenylpropane 
• 54655-07-1 lithium trimethylsilylacetylenide 
• 104-53-0 3-phenyl-propionaldehyde 
• 1066-54-2 trimethylsilylacetylene 
• 66950-73-0 3-phenylpropyl 1-trifluoromethanesulfonate 
• 122-97-4 3-Phenyl-1-propanol 
• 60-12-8 2-phenylethanol 
• 110211-31-9 Acetic acid 1-phenethyl-3-trimethylsilanyl-prop-2-ynyl ester 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 1554260-58-0 (9-(4-chlorophenyl)-6,7-dihydro-5H-benzo[7]annulen-8-yl)-diphenylphosphine oxide 
• 1554260-59-1 (E)-(1-(4-chlorophenyl)-5-phenylpent-1-en-2-yl)-diphenylphosphine oxide 
• 1554260-80-8 C₂₉H₂₆ClOP 
• 1554260-28-4 1-chloro-4-(5-phenylpent-1-yn-1-yl)benzene 
• 1823-14-9 5-phenyl-1-pentyne 
• 135939-54-7 (Z)-trimethyl(5-phenylpent-1-en-1-yl)silane 
• 136859-84-2 C₂₉H₂₆Se₃ 
• 136859-79-5 5-phenyl-1-phenylselenopent-1-yne 
• 121572-26-7 phenyl (5-phenylpent-1-ynyl) sulfide 

Relevant articles and documents

Nickel-catalyzed cross-coupling of primary alkyl halides with phenylethynyl- and trimethylsilyethynyllithium reagents

A highly efficient alkyl-alkynyl coupling system is described which is promoted by a well-defined and moisture-stable pincer complex [NiCl{C 6H3-2,6-(OPPh2)2}] (1). Non-activated alkyl halides could be efficient

Titanium-Promoted Cross-Coupling for the Selective Synthesis of Polysubstituted, Conjugated Amides

α,β-Unsaturated amides are important building blocks and are key structural elements in a number of biologically active natural products. Despite their importance and prevalence, few methods exist to prepare conjugated amides directly and modularly. To address this gap, a titanium-promoted coupling of alkynes and isocyanates has been developed. The method is highly stereoselective, producing only the E isomer with good chemoselectivity and regioselectivity (>95/5), for unsymmetrical internal alkynes that contain a steric bias. The reactive titanacyclopentene intermediate formed from the coupling of the alkyne and isocyanate was additionally reacted with various electrophiles to access tetrasubstituted enamides.

Manganese(III)-mediated selective diphenylphosphinoyl radical reaction of 1,4-diaryl-1-butynes for the synthesis of 2-phosphinoylated 3,4- dihydronaphathalenes

A diphenylphosphinoyl radical-initiated sequential reaction of 1,4-diaryl-1-butynes and analogues is developed for the synthesis of 2-phosphinoylated 3,4-dihydronaphathalenes and related compounds.