110316-24-0Relevant articles and documents
On the Mechanism of the Chorismate Mutase Reaction
Guilford, William J.,Copley, Shelley D.,Knowles, Jeremy R.
, p. 5013 - 5019 (1987)
To probe the mechanistic pathway of the reaction catalyzed by chorismate mutase, the secondary tritium isotope effect at C-4 of chorismate, kH/kT, has been determined.The small inverse effect of 0.96 rules out pathways that involve g
The Raction of Acetyliron 5-C5H5)Fe(CO)(PPh3)(COCH3)> with Sugar Aldehydes. New Synthesis of Deoxysugars
Pakulski, Zbigniew,Zamojski, Aleksander
, p. 871 - 908 (2007/10/02)
Aldol reactions of sugar aldehydes (5-13) with enolate 2 of racemic and both enantiomeric forms of acetyliron were investigated.The steric course of reactions depended strongly on the counterions used.High stereocontrol was achieved with the following cat