110474-22-1

Basic information

• Product Name: (1R,4R,8R)-8-Methylsulfanyl-4-(toluene-4-sulfinyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one
• CAS NO: 110474-22-1
• Molecular Weight: 308.422
• Mol File: 110474-22-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,4R,8R)-8-Methylsulfanyl-4-(toluene-4-sulfinyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R,8R)-8-Methylsulfanyl-4-(toluene-4-sulfinyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one(110474-22-1)
• EPA Substance Registry System: (1R,4R,8R)-8-Methylsulfanyl-4-(toluene-4-sulfinyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one(110474-22-1)

Safety Data

• Hazardous Substances Data: 110474-22-1(Hazardous Substances Data)

Upstream product

• 1822-74-8 methyl vinyl sulfide 
• 99268-86-7 (+/-)-3-p-toluenesulfinyl-2-pyrone 

Downstream Products

• 110474-23-2 (3R,4R,6R)-3,4-Dihydroxy-6-methylsulfanyl-cyclohex-1-enecarboxylic acid methyl ester 

Relevant articles and documents

Highly Stereocontrolled Synthesis of Some Polyfunctionalized Cyclohexenes. A Short Formal Total Synthesis of (+/-)-Chorismic Acid

Lewis acid catalysis or high pressure is an effective means for promoting stereocontrolled 2 + 4 cycloaddition between pyrone sulfoxide 1 and vinyl ethers and vinyl thioethers.The bridged, bicyclic lactone cycloadducts are versatile synthons carrying much