110480-94-9

Basic information

• Product Name: cyclopentylphenylmethanol
• CAS NO: 110480-94-9
• Molecular Weight: 176.258
• Mol File: 110480-94-9.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 286.8±9.0 °C(Predicted)
• Density: 1.066±0.06 g/cm3(Predicted)
• CAS DataBase Reference: cyclopentylphenylmethanol(CAS DataBase Reference)
• NIST Chemistry Reference: cyclopentylphenylmethanol(110480-94-9)
• EPA Substance Registry System: cyclopentylphenylmethanol(110480-94-9)

Safety Data

• Hazardous Substances Data: 110480-94-9(Hazardous Substances Data)

Upstream product

• 5422-88-8 phenyl cyclopentyl ketone 
• 60-29-7 diethyl ether 
• 286-20-4 cyclohexane-1,2-epoxide 
• 32916-51-1 cyclopentylmagnesium chloride 
• 100-52-7 benzaldehyde 
• 33240-34-5 cyclopentylmagnesium bromide 
• 3900-93-4 2-cyclopentyl-2-phenylacetic acid 
• 36140-18-8 dicyclopentylboron chloride 
• 3400-45-1 cyclopentanecarboxylic acid 
• 71-43-2 benzene 
• 1144522-07-5 C₁₉H₂₉BO₅S 
• 100-59-4 phenylmagnesium chloride 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 287-92-3 Cyclopentane 

Downstream Products

• 104620-56-6 (Cyclopentyl-methoxymethoxy-methyl)-benzene 
• 4410-78-0 (cyclopentylmethyl)benzene 
• 4410-77-9 benzylidenecyclopentane 
• 15507-35-4 1-benzylcyclopentene 
• 24260-06-8 cyclopentyl-phenylmethyl chloride 
• 117983-38-7 1-<<<(1'-cyclopentylphenyl)methyl>oxy>methyl>-2-<(hydroxyimino)methyl>-3-methylimidazolium chloride 
• 1396747-40-2 R-α-cyclopentyl(phenyl)methyl acetate 
• 1415394-01-2 C₁₄H₁₈O₂ 
• 1236375-74-8 C₁₅H₂₀O₂ 
• 94310-41-5 N-(cyclopentyl-phenyl-methyl)-benzamide 
• 5422-88-8 phenyl cyclopentyl ketone 
• 23459-36-1 1-phenyl-cyclopentylmethylamine 

Relevant articles and documents

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Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents

A hybrid transition-metal/radical process is described that results in the addition of organozinc reagents and alkyl halides across alkenyl boron reagents in an enantioselective catalytic fashion. The reaction can be accomplished both intermolecularly and intramolecularly, providing useful product yields and high enantioselectivities in both manifolds.

Ir(NHC)-Catalyzed Synthesis of β-Alkylated Alcohols via Borrowing Hydrogen Strategy: Influence of Bimetallic Structure

Multi N-heterocyclic carbene(NHC)-modified iridium catalysts were employed in the β-alkylation of alcohols; dimerization of primary alcohols (Guerbet reaction), cross-coupling of secondary and primary alcohols, and intramolecular cyclization of alcohols. Mechanistic studies of Guerbet reaction, including kinetic experiments, mass analysis, and density functional theory (DFT) calculation, were employed to explain the fast reaction promoted by bimetallic catalysts, and the dramatic reactivity increase of monometallic catalysts at the late stage of the reaction. (Figure presented.).

Coupling Reaction between Aldehydes and Non-Activated Hydrocarbons via the Reductive Radical-Polar Crossover Pathway

Herein, we describe the generation of an organochromium-type carbanion species from a non-activated C-H bond and its nucleophilic addition to aldehydes. The catalytic carbanion generation occurred through formal deprotonation of a non-activated C-H bond under mild conditions and did not need the prefunctionalization or anion stabilizing group. Carbon radical intermediates generated by decatungstate photocatalyst-mediated hydrogen abstraction were captured by a chromium salt with the reductive radical-polar crossover reaction to produce organochromium carbanions.