110598-48-6

Basic information

• Product Name: [(Z)-1-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane
• Synonyms: [(Z)-1-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane
• CAS NO: 110598-48-6
• Molecular Weight: 220.387
• Mol File: 110598-48-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [(Z)-1-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: [(Z)-1-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(110598-48-6)
• EPA Substance Registry System: [(Z)-1-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(110598-48-6)

Safety Data

• Hazardous Substances Data: 110598-48-6(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 99966-31-1 10-((Z)-1-Trimethylsilanyl-propenyl)-9-oxa-10-bora-bicyclo[3.3.2]decane 
• 6224-91-5 trimethyl(prop-1-ynyl)silane 
• 696-62-8 para-iodoanisole 

Relevant articles and documents

The efficient stereoselective synthesis of Z-vinylsilanes through the Suzuki-Miyaura coupling of Z-(α-silylvinyl)borinates

Air-stable Z-(α-silylvinyl)borinates (2), easily prepared in a hydroboration-oxidation sequence from I provide a particularly effective route to Z-vinylsilanes (3, 59-97%) through Suzuki-Miyaura coupling.

PALLADIUM-CATALYSED REDUCTIVE ADDITION OF ARYL IODIDES TO ARYL AND ALKYLETHYNYLSILANES: A STEREO AND REGIOSELECTIVE ROUTE TO FUNCTIONALIZED 2,2-DISUBSTITUTED VINYLSILANES

Aryl and alkylethynylsilanes are converted into 2,2-disubstituted vinylsilanes containing various common functional groups in the presence of aryl iodides, a palladium catalyst, formic acid, and a tertiary or secondary amine with high stereoselectivity an