110623-99-9

Basic information

• Product Name: 4-methylphenyl 3-(ethylenedioxy)-3-phenylpropanoate
• Synonyms: 4-methylphenyl 3-(ethylenedioxy)-3-phenylpropanoate
• CAS NO: 110623-99-9
• Molecular Weight: 298.339
• Mol File: 110623-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-methylphenyl 3-(ethylenedioxy)-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methylphenyl 3-(ethylenedioxy)-3-phenylpropanoate(110623-99-9)
• EPA Substance Registry System: 4-methylphenyl 3-(ethylenedioxy)-3-phenylpropanoate(110623-99-9)

Safety Data

• Hazardous Substances Data: 110623-99-9(Hazardous Substances Data)

Upstream product

• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 27773-03-1 ethyl 3,3-(ethylenedioxy)-3-phenylpropanoate 

Downstream Products

• 29976-82-7 1-(2-hydroxy-5-methylphenyl)-3-phenylpropane-1,3-dione 
• 29976-75-8 6-methylflavone 
• 110624-02-7 3-(ethylenedioxy)-1-(2-hydroxy-5-methylphenyl)-3-phenyl-1-propanone 
• 67801-43-8 4-methylphenyl benzoylacetate 

Relevant articles and documents

PHOTOLYSIS OF CYCLIC ACETALS OF ARYL BENZOYLACETATES AS THE KEY STEP IN A NEW SYNTHESIS OF FLAVONES

Although the yields found for the photo-Fries rearrangement of the aryl benzoylacetates 1 are poor, blocking of the carbonyl group, as in the related acetal derivatives 3, results in a substantial preparative improvement.Thus, the o-hydroxydibenzoylmethanes 2 are obtained from 1 with an average yield of 18percent, while the corresponding acetals 4 are obtained from 3 with an average yield of 58 percent.Compounds 4 are efficiently converted into flavones 8 by means of wet silica gel, through hydrolysis of the acetal moiety and subsequent cyclization of the resulting o-hydroxydibenzoylmethanes 2.