1107-69-3Relevant articles and documents
Hydrolysis of 2-alkoxyalk-2-enals
Mamashvili,Keiko,Sarapulova,Voronkov
, p. 2465 - 2467 (1998)
Hydrolysis of 2-alkoxyalk-2-enals with equimolar amount of water (in an organic solvent) and with an excess of water has been studied with the aim of synthesizing 2-oxopropanal (methylglyoxal). 2-Oxopropanal obtained in an excess of water exists in the hy
COMPARATIVE REACTIVITY OF α-ACETOXYACROLEIN AND α-ETHOXYACROLEIN
Keiko, N. A.,Musorina, T. N.,Frolov, Yu. L.,Shulunova, A. M.,Chuvashov, Yu. A.,Voronkov, M. G.
, p. 1634 - 1636 (2007/10/02)
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KINETICS AND MECHANISM OF THE REDOX REACTION OF THALLIC SULPHATE WITH ACROLEINE
Treindl, Ludovit,Melichercik, Milan
, p. 1173 - 1181 (2007/10/02)
The stoichiometry, kinetics and mechanism of the redox reaction of thallic sulphate with acroleine in aqueous sulphuric acid or in aqueous dioxane solutions were studied.The acroleine molecule is oxidised with Tl(III) ions in two consecutive one-electron step to glyceraldehyde.The corresponding rate equation is -d/dt = kn , where n = 0-2.The zeroth reaction order with respect to thallic ions is attributed to a slow enolization of the hydrated acroleine, which is the rate-determining step preceding the redox reaction proper.