110814-27-2

Basic information

• Product Name: cis-2,3-bis(trimethylsilyl)cyclopropan-1-one
• Synonyms: cis-2,3-bis(trimethylsilyl)cyclopropan-1-one
• CAS NO: 110814-27-2
• Molecular Weight: 200.428
• Mol File: 110814-27-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-2,3-bis(trimethylsilyl)cyclopropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2,3-bis(trimethylsilyl)cyclopropan-1-one(110814-27-2)
• EPA Substance Registry System: cis-2,3-bis(trimethylsilyl)cyclopropan-1-one(110814-27-2)

Safety Data

• Hazardous Substances Data: 110814-27-2(Hazardous Substances Data)

Upstream product

• 4071-85-6 trimetylsilylketene 
• 18107-18-1 diazomethyl-trimethyl-silane 

Downstream Products

• 18178-59-1 (E)-1,2-bis(trimethylsilyl)ethene 
• 1473-61-6 (Z)-1,2-bis(trimethylsilyl)ethylene 

Relevant articles and documents

Reaction of silyl- and germyl-ketenes with silyldiazomethanes

The reaction of trialkylsilyl- and trialkylgermyl-ketenes with trialkylsilyldiazomethanes proceeds stereoselectively to give one of two feasible stereomers, the Z-2,3-bis(Si,Ge)-substituted cyclopropanone.The addition of nucleophilic reagents such as benzyl alcohol, LiAlH4 or (trimethylsilyl)dialkylphosphites is highly stereoselective and is a convenient method for assigning the stereochemical configuration of 2,3-substituted cyclopropanones.

REACTION OF (TRIMETHYLSILYL)KETENE WITH DIAZO(TRIMETHYLSILYL)METHANE

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