110893-39-5Relevant articles and documents
THE SYNTHESIS AND PROPERTIES OF 1,4-DIKETO-PYRROLOPYRROLES
Iqbal, A.,Jost, M.,Kirchmayr, R.,Pfenninger, J.,Rochat, A.,Wallquist, O.
, p. 615 - 644 (2007/10/02)
Syntheses and mechanistic aspects of formation of 1,4-Diketopyrrolopyrroles (DPP) are discussed.The chemical reactivity of this novel class of heterocycles is illustrated by specific electrophilic aromatic and N-substitution reactions, as well as by nucleophilic transformations of the bicyclic lactam carbonyl group.X-ray structural analysis of the diphenyl-DPP molecule reveals significant intermolecular hydrogen bonding and ?-? interactions in the solid state.