110943-74-3Relevant articles and documents
A (3 - alkoxy - 4 - hydroxy) - cyclohexyl acetal glycol and its isomers of use
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, (2017/08/26)
The present invention discloses a (3-alkoxy-4-hydroxy)-cyclohexyl methylal diol, an (3-hydroxy-4-alkoxy)-cyclohexyl methylal diol and synthesis methods and use therefor. The (3-alkoxy-4-hydroxy)-cyclohexyl methylal diol and (3-hydroxy-4-alkoxy)-cyclohexyl methylal diol can be used for synthesis of a variety of vanillin and iso-vanillin. Compared to the existing synthetic method, the synthesis method has simple steps, and less discharge of "three wastes".
Practical Ligand-Free Copper-Catalysed Short-Chain Alkoxylation of Unactivated Aryl Bromides
Guo, Ying,Fan, Xue-Min,Nie, Min,Liu, Hong-Wei,Liao, Dao-Hua,Pan, Xian-Dao,Ji, Ya-Fei
, p. 4744 - 4755 (2015/08/03)
An efficient and practical short-chain alkoxylation of unactivated aryl bromides has been developed with special attention focussed on the applicability of the reaction. Sodium alkoxide is used as the nucleophile, and the corresponding alcohol as the solvent. The reaction requires neither precious metals nor organic ligands. It uses a catalytic system consisting of copper(I) bromide as a catalyst, the corresponding alkyl formate as a noncontaminating cocatalyst, and lithium chloride as an additive. A wide range of substrates and test cases highlight the synthetic utility of the approach. Considering the commercial accessibility and affordability of the feedstocks, this protocol shows promise as a new alternative for the sustainable preparation of aryl alkyl ethers.
Synthesis, structure, thermal and nonlinear optical properties of a series of novel D-π-A chromophores with varying alkoxy substituents
Kosilkin, Ilya V.,Hillenbrand, Emily A.,Tongwa, Paul,Fonari, Alexandr,Zazueta, Joel,Fonari, Marina S.,Antipin, Mikhail,Dalton, Larry R.,Timofeeva, Tatiana
experimental part, p. 356 - 365 (2012/02/03)
Six new derivatives of the previously reported chromophore 2-(3-(4-hydroxystyryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile (OH1) with potential application in electrooptics were synthesized and their crystal structures characterized using a single c