111-47-7 Usage
Description
Propyl sulfide, also known as di-n-propyl sulfide, is a garlic organosulfide and a clear colorless liquid. It is an organosulfur compound that can be derived from garlic and has various applications in different industries due to its unique properties.
Uses
Used in Organic Synthesis:
Propyl sulfide is used as an intermediate in the synthesis of various organic compounds. Its chemical properties make it a versatile building block for creating a wide range of molecules with different functionalities.
Used in Fragrance Industry:
Propyl sulfide is used as a component in the daily fragrance industry. Its pleasant aroma and stability make it a suitable addition to perfumes and other scented products.
Used in Pharmaceutical Industry:
As a garlic organosulfide, propyl sulfide may have potential applications in the pharmaceutical industry, particularly in the development of drugs targeting various health conditions. However, more research is needed to fully understand its therapeutic potential and safety profile.
Synthesis Reference(s)
Canadian Journal of Chemistry, 51, p. 1419, 1973 DOI: 10.1139/v73-213Organic Syntheses, Coll. Vol. 2, p. 547, 1943Tetrahedron Letters, 20, p. 3995, 1979
Purification Methods
Wash the sulfide with aqueous 5% NaOH, then water. Dry it with CaCl2 and distil it from Na [Dunstan & Griffiths J Chem Soc 1344 1962]. [Beilstein 1 IV 1452.]
Check Digit Verification of cas no
The CAS Registry Mumber 111-47-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 1 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 111-47:
(5*1)+(4*1)+(3*1)+(2*4)+(1*7)=27
27 % 10 = 7
So 111-47-7 is a valid CAS Registry Number.
InChI:InChI=1/C6H14S/c1-3-5-7-6-4-2/h3-6H2,1-2H3
111-47-7Relevant articles and documents
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Nishimura,Kawamoto
, p. 274,275 (1972)
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Nishimura,H. et al.
, p. 307 - 313 (1971)
Gladysz et al.
, p. 2329,2334 (1979)
Kubota,Yamamoto
, p. 3622,3623 (1978)
Bis(tributyltin) Sulfide: An Effective and General Sulfur-Transfer Reagent
Harpp, David N.,Gingras, Marc,Aida, T.,Chan, T. H.
, p. 1122 - 1124 (1987)
Bis(tributyltin) sulfide acts efficiently to transfer the sulfur atom as S(2-) to a variety of halide substrates to afford the corresponding symmetrical sulfides in good overall yield.
A process for the preparation of isoflavones propanethiol
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Paragraph 0052; 0053, (2017/04/03)
The invention discloses a method for synthesizing isopropyl mercaptan from propylene and hydrogen sulfide. According to the method, a heat insulation type fixed bed reactor is used and isopropyl mercaptan is synthesized of hydrogen sulfide and propylene in the presence of a solid acid catalyst according to a continuous production process. The method disclosed by the invention has the advantages that the reaction conditions are easy to control, the yield is high, the process is simple, and the environmental pollution is reduced.
Hydrogenation of sulfoxides to sulfides under mild conditions using ruthenium nanoparticle catalysts
Mitsudome, Takato,Takahashi, Yusuke,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
supporting information, p. 8348 - 8351 (2014/08/18)
The first demonstration of the hydrogenation of sulfoxides under atmospheric H2 pressure is reported. The highly efficient reaction is facilitated by a heterogeneous Ru nanoparticle catalyst. The mild reaction conditions enable the selective hydrogenation of a wide range of functionalized sulfoxides to the corresponding sulfides. The high redox ability of RuO x nanoparticles plays a key role in the hydrogenation.
