111002-69-8

Basic information

• Product Name: (2S,3R,4S)-2-Benzyloxy-4-methoxy-4-methyl-hex-5-yn-3-ol
• CAS NO: 111002-69-8
• Molecular Weight: 248.322
• Mol File: 111002-69-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S)-2-Benzyloxy-4-methoxy-4-methyl-hex-5-yn-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S)-2-Benzyloxy-4-methoxy-4-methyl-hex-5-yn-3-ol(111002-69-8)
• EPA Substance Registry System: (2S,3R,4S)-2-Benzyloxy-4-methoxy-4-methyl-hex-5-yn-3-ol(111002-69-8)

Safety Data

• Hazardous Substances Data: 111002-69-8(Hazardous Substances Data)

Upstream product

• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 111868-91-8 1-lithio-3-methoxy-1,2-butadiene 
• 50285-32-0 1-Methyl-1-methoxyallen 

Relevant articles and documents

Stereoselective Syntheses of Alcohols, XXVI. - Synthesis of 3-Methyl-2,6-dideoxyhexoses by Addition of an Allenyltitanium Reagent to Aldehydes.

In contrast to the nonregioselective addition of 3-methoxy-3-methylallenyllithium (8) to aldehydes the corresponding titanium reagent 14 produced only propargylic type adducts.The products resulting on addition of 14 to L-2-(benzyloxy)propionaldehyde have been converted into 3-O-methyl-3-methyl-2,6-dideoxyhexoses 23 and 25 of arabino and xylo configuration.