111008-64-1

Basic information

• Product Name: Benzoic acid, 4-methyl-, methylene ester
• CAS NO: 111008-64-1
• Molecular Formula: C17H16O4
• Molecular Weight: 284.312
• Mol File: 111008-64-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-methyl-, methylene ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-methyl-, methylene ester(111008-64-1)
• EPA Substance Registry System: Benzoic acid, 4-methyl-, methylene ester(111008-64-1)

Safety Data

• Hazardous Substances Data: 111008-64-1(Hazardous Substances Data)

Upstream product

• 99-94-5 p-Toluic acid 
• 74-95-3 1,1-dibromomethane 
• 75-09-2 dichloromethane 
• 104-87-0 4-methyl-benzaldehyde 
• 75-11-6 diiodomethane 
• 16518-25-5 potassium p-methyl benzoate 

Relevant articles and documents

Microwave-assisted, facile, rapid and solvent-free one pot two-component synthesis of some special acylals

A facile, rapid and solvent-free method for the conversion of acids and dihalomethane to the corresponding methylene diesters (acylals) using microwave as activators or assistor, is reported. This method is particularly powerful for the diesterification o

Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethane or dichloropropane under mild conditions

Dichloromethane (DCM) as a C1 source has been discovered: methylene diesters from DCM and carboxylic acids or aldehydes with TBHP in water were efficiently synthesized. The reactions proceed under mild conditions and afford both aliphatic and aromatic met

DBU-CH3I, a potential substitute for CH2N2 in the preparation of methyl esters and methyl aryl ethers: Studies with assorted acids

DBU-CH3I has been poised to be a substitute for diazomethane in the preparation of methyl esters from carboxylic acids. The reactions can be carried out in commercial untreated acetone and acetonitrile, which have been exemplified with several methyl esters, otherwise it is difficult to prepare. Bis-esterification using diiodomethane can also be achieved in a similar fashion. Sufficiently acidic phenols are also conveniently O-methylated by the method. Copyright Taylor & Francis Group, LLC.