111015-21-5

Basic information

• Product Name: phenylglyoxylate du 1-(9-anthryl)ethanol
• CAS NO: 111015-21-5
• Molecular Weight: 354.405
• Mol File: 111015-21-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenylglyoxylate du 1-(9-anthryl)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: phenylglyoxylate du 1-(9-anthryl)ethanol(111015-21-5)
• EPA Substance Registry System: phenylglyoxylate du 1-(9-anthryl)ethanol(111015-21-5)

Safety Data

• Hazardous Substances Data: 111015-21-5(Hazardous Substances Data)

Upstream product

• 25726-04-9 phenylglyoxylyl chloride 
• 74928-67-9 9-(1-hydroxyethyl)anthracene 

Downstream Products

• 111015-33-9 2-Hydroxy-2-phenyl-propionic acid 1-anthracen-9-yl-ethyl ester 

Relevant articles and documents

UTILISATION DE LA SYNTHESE ATROLACTIQUE POUR L'EVALUATION DE L'EFFICACITE D'INDUCTEURS DE SYNTHESE ASYMETRIQUE.

Atrolactic syntheses have been carried out to evaluate the potentiality, in asymmetric syntheses, of chiral inducers.The (dl)-hydroxyhelicenes 1, 2, the (dl) sec. alcohols 3-12 and the (dl)phenolic binaphtyl compound 15 have been used as inducers.The d.e. are collected in table I (6-100percent).The atrolactic asymmetric synthesis has also been carried out using three optically active inducers, namely : (-)-quinine 13, (-)-10,11-dihydroquinine 14, and R(-)-2,2,2-trifluoro-1-(9-anthryl)ethanol 6.Diastereometric and enantiomeric excesses equal or greater than 88percent have been obtained in six cases out of sixteen : (dl)-2-hydroxyheptahelicene 1 (d.e = 100percent +/-2), (1-naphtyl)-(9-anthryl)methanol 3 (d.e = 90percent) ; 2,2,2-trichloro-1-(9-anthryl)ethanol 7 (d.e = 100percent +/-2), 2,2,2-tribromo-1-(9-anthryl)ethanol 8 (d.e = 100percent +/-2), (-)-quinine 13 (e.e = 95.5percent), and (-)-2,2,2-trifluoro-1-(9-anthryl)ethanol 6 (e.e = 88percent).