111034-84-5

Basic information

• Product Name: 3-hydroxytricyclo<4.3.1.1^3,8>undec-4-yl benzoate
• Synonyms: 3-hydroxytricyclo<4.3.1.1^3,8>undec-4-yl benzoate
• CAS NO: 111034-84-5
• Molecular Weight: 286.371
• Mol File: 111034-84-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-hydroxytricyclo<4.3.1.1^3,8>undec-4-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-hydroxytricyclo<4.3.1.1^3,8>undec-4-yl benzoate(111034-84-5)
• EPA Substance Registry System: 3-hydroxytricyclo<4.3.1.1^3,8>undec-4-yl benzoate(111034-84-5)

Safety Data

• Hazardous Substances Data: 111034-84-5(Hazardous Substances Data)

Upstream product

• 2094-74-8 1-Adamantanecarbaldehyde 
• 36967-85-8 benzoyl triflate 

Relevant articles and documents

Ring-Expansion of Bridgehead Aldehydes with 1-Adamantanecarbonyl Cation or Benzoyl Trifluoromethanesulfonate: A New Route to Bicyclic and Tricyclic 1,2-Diols

Acylation of bridgehead aldehydes with 1-adamantanecarbonyl cation generated from 1-adamantyl cation and carbon monoxide, or with benzoyl trifluoromethanesulfonate, in the presence of trifluoromethanesulfonic acid causes ring-expansion of the aldehydes by one carbon atom.Work-up of the reaction mixture with water affords a bridgehead alcohol containing the acyloxy group on the vicinal carbon, which on saponification gives a vicinal glycol in good overall yields.For example, bicycloheptane-1-carbaldehyde gives bicyclooctane-1,2-diol which is not easily accessible by the other methods.