111042-72-9

Basic information

• Product Name: (2S)-2,3-dimethylbutyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate
• CAS NO: 111042-72-9
• Molecular Weight: 318.336
• Mol File: 111042-72-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S)-2,3-dimethylbutyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2,3-dimethylbutyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate(111042-72-9)
• EPA Substance Registry System: (2S)-2,3-dimethylbutyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate(111042-72-9)

Safety Data

• Hazardous Substances Data: 111042-72-9(Hazardous Substances Data)

Upstream product

• 122778-32-9 (1R,3R,4S)-p-menthan-3-yl (2R)-2-hydroxymethyl-3-methylbutyrate 
• 122778-52-3 (S)-2-Chloromethyl-3-methyl-butyric acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 122778-53-4 (S)-2,3-Dimethyl-butyric acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 122778-25-0 (1R,3R,4S)-p-menthan-3-yl hydrogen isopropylmalonate 
• 111042-78-5 (1R,3R,4S)-8-phenyl-p-menthan-3-yl hydrogen isopropylmalonate 
• 601-79-6 isopropylmalonic acid 
• 15071-36-0 (R)-2,3-dimethylbutan-1-ol 
• 20445-31-2 MTPA 
• 15071-36-0 (2S)-(+)-2,3-dimethyl-1-butanol 
• 17257-71-5 (S)-Mosher acid 
• 111042-70-7 (1R,3R,4S)-8-phenyl-p-menthan-3-yl (2R)-2-hydroxymethyl-3-methylbutyrate 

Relevant articles and documents

Asymmetric Syntheses of Chiral Propane-1,3-diols Starting from Malonic Acid

Syntheses of chiral intermediates having one tertiary asymmetric centre were carried out via chiral half-esters of monoalkylmalonic acids.The menthyl half-ester of ethylmalonic acid afforded a single diastereoisomer through crystallisation-induced asymmetric transformation (second-order asymmertic transformation).Furthermore enantioselective preparation of unsymmertical propane-1,3-diol derivatives was achieved by the use of 8-phenylmenthyl half-esters.