111263-94-6

Basic information

• Product Name: (3S,5R,8R,9S,10S,13S,14S)-16-Benzenesulfinyl-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hexadecahydro-cyclopenta[a]phenanthren-17-one
• Synonyms: (3S,5R,8R,9S,10S,13S,14S)-16-Benzenesulfinyl-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hexadecahydro-cyclopenta[a]phenanthren-17-one
• CAS NO: 111263-94-6
• Molecular Weight: 498.727
• Mol File: 111263-94-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,5R,8R,9S,10S,13S,14S)-16-Benzenesulfinyl-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hexadecahydro-cyclopenta[a]phenanthren-17-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5R,8R,9S,10S,13S,14S)-16-Benzenesulfinyl-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hexadecahydro-cyclopenta[a]phenanthren-17-one(111263-94-6)
• EPA Substance Registry System: (3S,5R,8R,9S,10S,13S,14S)-16-Benzenesulfinyl-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hexadecahydro-cyclopenta[a]phenanthren-17-one(111263-94-6)

Safety Data

• Hazardous Substances Data: 111263-94-6(Hazardous Substances Data)

Upstream product

• 571-31-3 Epietiocholanolone 
• 670-98-4 methyl benzenesulfinate 
• 111264-15-4 3β-hydroxy-5β-androstan-17-one 3-tetrahydropyranyl ether 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 111119-51-8 3β-hydroxy-16ξ-phenylsulfinyl-5β-androstan-17-one 

Relevant articles and documents

Cardiotonic steroids. Part 11. An Improved Procedure for Preparation of Androst-15-en-17-one Derivatives

α,β-Unsaturated ketones 3a-3c were prepared from the corresponding saturated ketones (1a-1d) by means of sulfinylation with methyl benzenesulfinate and pyrolysis of intermediate phenylsulfinyl derivatives (2a, 2e, 2f).