111268-67-8

Basic information

• Product Name: 4-bromo-2,6-diphenyl-tetrahydro-2H-pyran
• Synonyms: 4-bromo-2,6-diphenyl-tetrahydro-2H-pyran
• CAS NO: 111268-67-8
• Molecular Weight: 317.225
• Mol File: 111268-67-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 4-bromo-2,6-diphenyl-tetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-2,6-diphenyl-tetrahydro-2H-pyran(111268-67-8)
• EPA Substance Registry System: 4-bromo-2,6-diphenyl-tetrahydro-2H-pyran(111268-67-8)

Safety Data

• Hazardous Substances Data: 111268-67-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 104-53-0 3-phenyl-propionaldehyde 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 106-95-6 allyl bromide 
• 85551-57-1 (R)-1-Phenylbut-3-en-1-ol 
• 762-72-1 allyl-trimethyl-silane 

Relevant articles and documents

SYNTHESIS OF 4-HALOTETRAHYDROPYRANS FROM ALLYLSILANES AND CARBONYL COMPOUNDS IN THE PRESENCE OF LEWIS ACIDS

An unexpected behaviour of the rection of allylsilanes and carbonyl compounds allowed the stereospecific preparation of differently substituted 4-halotetrahydropyrans with an "all cis" configuration.

Direct synthesis of tetrahydropyrans via one-pot Babier-Prins cyclization of allylbromide with carbonyl compounds promoted by RTILs BPyX/SnX′2 or BBIMBr/SnBr2

Tetrahydropyran compounds can be directly synthesized from allylbromide and carbonyl compounds by means of one-pot Babier-Prins cyclization promoted by BPyX/SnX′2 or BBIMBr/SnBr2 complex (functionalized RTILs) under solvent-free cond

Diastereoselective syntheses via Prins cyclization, crystal structures determination and theoretical studies of cis-2,6-diphenyl-4- hydroxytetrahydropyran and analogues

We report in this article the diastereoselective syntheses of tetrahydropyranyl derivatives 1-5, its cis configurational ascertainment by spectroscopy and finally the crystal structures determination that unequivocally shows the 1-5 configurations and its