111317-33-0Relevant articles and documents
HETEROAROMATIC AZO-ACTIVATED NUCLEOPHILIC SUBSTITUTIONS. THE REACTION OF 4-(p-METHOXYPHENYLAZO)PYRIDINIUM METHIODIDE WITH PIPERIDINE IN DIMETHYL SULPHOXIDE
Onyido, Ikenna,Ubochi, Collins I.
, p. 313 - 317 (2007/10/02)
The azopyridinium-activated phenyl methyl ether, 1, undergoes nucleophilic attack by piperidine in dimethyl sulphoxide predominantly at the aryl carbon centre in a reaction that is base catalyzed and faster than the corresponding reaction of the dinitro-activated analogue, 2, by more than two decades.