111571-96-1

Basic information

• Product Name: 1-amino-9-benzyl-2-methylcarbazole
• CAS NO: 111571-96-1
• Molecular Weight: 286.376
• Mol File: 111571-96-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-amino-9-benzyl-2-methylcarbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-amino-9-benzyl-2-methylcarbazole(111571-96-1)
• EPA Substance Registry System: 1-amino-9-benzyl-2-methylcarbazole(111571-96-1)

Safety Data

• Hazardous Substances Data: 111571-96-1(Hazardous Substances Data)

Upstream product

• 3377-71-7 N-benzylindole 
• 102334-32-7 2-(Diethylphosphonooxy)-2-methyl-3-butenenitrile 

Relevant articles and documents

Allylic Rearrangement of Cyanophosphates. III. Reaction of Acyclic Enone Cyanophosphates

Boron trifluoride-catalyzed allylic rearrangement of α,β-unsaturated ketone cyanophosphates (2, 6 and 12) gave (Z)-4-diethylphosphonooxy-2-butenenitriles (3, 8 and 13), while α,β-unsaturated aldehyde cyanophosphates (17a-c) afforded (E)-4-diethylphosphonooxy-2-butenenitriles (18a-c) stereoselectively.The stereo- and regioselective reaction of 2 with several kinds of aromatics in the presence of boron trifluoride etherate afforded (Z)-4-aryl-2-methyl-2-butenenitriles (20) via the SN2' reaction.On the other hand, treatment of 2 with 1-substituted indoles in the presence of boron trifluoride etherate gave 1-amino-2-methylcarbazole derivatives (23a-c).Keywords-α,β-unsaturated ketone; α,β-unsaturated aldehyde; cyanophosphate; allylic rearrangement; boron trifluoride etherate; 2-butenenitrile derivative; SN2' reaction; 1-aminocarbazole derivative