111679-77-7

Basic information

• Product Name: Benzenemethanol, a-(3,3-dimethyl-1-butynyl)-a-(1-methylethyl)-
• CAS NO: 111679-77-7
• Molecular Formula: C16H22O
• Molecular Weight: 230.35
• Mol File: 111679-77-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(3,3-dimethyl-1-butynyl)-a-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(3,3-dimethyl-1-butynyl)-a-(1-methylethyl)-(111679-77-7)
• EPA Substance Registry System: Benzenemethanol, a-(3,3-dimethyl-1-butynyl)-a-(1-methylethyl)-(111679-77-7)

Safety Data

• Hazardous Substances Data: 111679-77-7(Hazardous Substances Data)

Upstream product

• 104480-60-6 (3,3-dimethylbut-1-yn-1-yl)magnesium bromide 
• 611-70-1 phenyl isopropyl ketone 

Relevant articles and documents

PROPARGYL ORGANOMETALLIC COMPOUNDS. II. ALKYLATION OF SODIUM DERIVATIVES OF 1-ALKYL-1-ARYL-2-ALKYNES IN LIQUID AMMONIA

In most cases the alkylation of the sodium derivatives of 1-phenyl-1-alkyl-2-alkynes by methyl, ethyl, isopropyl, and tert-butyl bromides in liquid ammonia takes place preferentially at the sp2-hybridized carbon atom, and this leads to the formation of the corresponding acetylenes.The regioselectivity of the reaction is explained by the greater softness of the trigonal atom of the ambident propargyl anion and its smaller screening by the solvate shell compared with the diagonal atom.