111789-39-0

Basic information

• Product Name: 3-Octen-1-ol, 4-methylbenzenesulfonate, (Z)-
• CAS NO: 111789-39-0
• Molecular Formula: C15H22O3S
• Molecular Weight: 282.404
• Mol File: 111789-39-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Octen-1-ol, 4-methylbenzenesulfonate, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Octen-1-ol, 4-methylbenzenesulfonate, (Z)-(111789-39-0)
• EPA Substance Registry System: 3-Octen-1-ol, 4-methylbenzenesulfonate, (Z)-(111789-39-0)

Safety Data

• Hazardous Substances Data: 111789-39-0(Hazardous Substances Data)

Upstream product

• 100419-71-4 oct-3-ynyl 4-methylbenzenesulfonate 
• 18185-81-4 cis-3-octen-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1064196-59-3 (Z)-N-(oct-3-en-1-yl)-N-phenylacetamide 
• 53155-10-5 (E)-1-oct-3-enyl bromide 
• 53155-11-6 (3Z)-1-bromooct-3-ene 

Relevant articles and documents

Palladium porphyrin catalyzed hydrogenation of alkynes: Stereoselective synthesis of cis -alkenes

(Tetraphenylporphyrin)palladium was developed as a catalyst for the chemoselective and stereoselective hydrogenation of alkynes to cis-alkenes by the syn-addition of hydrogen. Alkynes containing various functional groups were tolerated in the reaction, which gave the corresponding cis-alkenes in good to excellent yields. Georg Thieme Verlag Stuttgart New York.

Syntheses of Monounsaturated Sex Pheromones of Lepidoptera via 3-Alkyn-1-ols

3-Alkyn-1-ols as intermediate synthons in the preparation of some Lepidoteran sex pheromones were utilized.Characteristic fragmentations reflecting the position of the triple bond were found in the mass spectra of 3-alkyn-1-ols and alkyn-1-yl acetates in contrast to 1-tert-butoxy-alkynes.A partial isomerization of 1-tosyloxy-3-(Z)-octene to 1-bromo-3-(E)-octene within the reaction with NaBr in DMF was noticed by GC and 13C-n.m.r., for which a mechanism involving homoconjugation in an intermediate non-classical carbonium ion was suggested.