1117975-52-6Relevant articles and documents
Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent
Chudasama, Vijay
, p. 44423 - 44426 (2015/06/02)
The unique properties of pentafluorophenyl vinyl sulfonate allow for a hitherto unmet feat to be realised; efficient and high yielding, metal-free, radical-based alkene hydroacylation employing aldehyde as limiting reagent. The optimised conditions are sh
Dioxygen mediated hydroacylation of vinyl sulfonates and sulfones on water
Chudasama, Vijay,Fitzmaurice, Richard J.,Ahern, Jenna M.,Caddick, Stephen
supporting information; experimental part, p. 133 - 135 (2010/04/01)
Herein we report a mild, facile method for the preparation of 1,4-keto-sulfonates and sulfones on water. Further synthetic manipulations can result in products that are not readily accessed by hydroacylation of electron rich alkenes.
