1118-03-2

Basic information

• Product Name: AZIDOTRIMETHYLTIN
• Synonyms: AZIDOTRIMETHYLTIN;TrimeThylTin azide;azidotrimethyltin(iv);TRIMETHYLTINAZIDE=AZIDOTRIMETHYLTIN;Trimethyltinazide, 97% (CH3)3SnN3 F.W.205,82;trimethylstannanylium:azide
• CAS NO: 1118-03-2
• Molecular Formula: C₃H₉N₃Sn
• Molecular Weight: 205.83
• Product Categories: Azide SourcesOrganometallic Reagents;Chemical Ligation;Click Chemistry;Organotin;Organotins
• Mol File: 1118-03-2.mol
• Article Data: 15

Chemical Properties

• Melting Point: 117-120 °C(lit.)
• Appearance: /
• CAS DataBase Reference: AZIDOTRIMETHYLTIN(CAS DataBase Reference)
• NIST Chemistry Reference: AZIDOTRIMETHYLTIN(1118-03-2)
• EPA Substance Registry System: AZIDOTRIMETHYLTIN(1118-03-2)

Safety Data

• Hazard Codes: T+,N
• Statements: 26/27/28-50/53
• Safety Statements: 26-27-28-45-60-61
• RIDADR: UN 3146 6.1/PG 2
• WGK Germany: 2
• Hazardous Substances Data: 1118-03-2(Hazardous Substances Data)

Usage

General Description

AZIDOTRIMETHYLTIN is a chemical compound that consists of a tin atom bonded to three methyl groups and one azide group. It is typically used as a precursor in the synthesis of various organic compounds. AZIDOTRIMETHYLTIN is known for its use in organic chemistry reactions, particularly in the synthesis of organotin compounds and in the modification of organic molecules. It is often used as a reagent in azide-alkyne cycloaddition reactions to form 1,2,3-triazole compounds. However, it is important to handle AZIDOTRIMETHYLTIN with caution, as it is highly toxic and can pose serious health hazards if mishandled.

InChI:InChI=1/3CH3.N3.Sn/c;;;1-3-2;/h3*1H3;;/q;;;-1;+1/rC3H9N3Sn/c1-7(2,3)6-5-4/h1-3H3

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 4648-54-8 trimethylsilylazide 
• 1068-74-2 Diethylamino-trimethyl-stannan 

Downstream Products

• 459842-49-0 N-[4,5-dimethyl-2-[2-methyl-4-(5-tetrazolyl)phenylmethyloxy]phenyl]-N-isobutyl-(5-methyl-2-furyl)sulfonylamide 
• 348639-11-2 2-[1-methyl-5-(1-trimethylstannanyl-1H-tetrazol-5-yl)-1H-indol-3-yl]-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine 
• 503857-50-9 2-[4-(Benzyloxy)phenyl]-1-cyclohexyl-5-(1H-tetrazol-5-yl)-1H-benzimidazole 
• 55408-10-1 1H-tetrazole-5-carboxylic acid ethyl ester 
• 317828-51-6 2-[(S)-1-Phenylethylamino]-4-[5-(tetrazol-5-yl)benzimidazol-1-yl]pyrimidine 
• 337521-78-5 2-Methyl-1-(6-(1H-1H-1,2,3,4-tetrazol-5-yl)-2-naphthyl)-1-(1-trityl-1H-imidazol-4-yl)-1-propanol 
• 169328-27-2 5-ethyl-2-imino-3-[2'-(1H-tetrazol-5-yl)biphenyl-4-yl]methyl-1,3,4-thiadiazoline.hydrochloride 
• 151327-04-7 7-[(N-Morpholinoethyl)amino]-5-propyl 6-[(2'-(1H-tetrazol-5-yl)biphenyl-4-yl)-methyl]pyrazolo[1,5-a]pyrimidine 
• 137419-91-1 7-Methyl-2-propyl-3-[4-(2-phenyl-2-(tetrazol-5-yl)ethyl)phenyl]methyl-3H-imidazo[4,5-b]pyridine 
• 61-82-5 3⁽⁵⁾-amino-1,2,4-triazole 
• 142014-86-6 7-Methyl-2-propyl-3-[[4-[2-(1H-tetrazol-5-yl)-3-furanyl]phenyl]methyl]imidazo[4,5-b]pyridine 
• 139481-58-6 ethyl 2-ethoxy-1-[[2'-(1H-tetrazol-5-yl)biphenyl-4-yl]-methyl]benzimidazole-7-carboxylate 
• 142017-12-7 5-chloro-3-(4-methylphenyl)-2-(1H-tetrazol-5-yl)thiophene 
• 137761-33-2 3-Butyl-5-(4-nitrobenzylthio)-4-[[4-[1-phenyl-1-(tetrazol-5-yl)methoxy]phenyl]methyl]-4H-1,2,4-triazole 

Related news

Adsorption structure and doping effect of AZIDOTRIMETHYLTIN (cas 1118-03-2) on graphene09/09/2019

The adsorption structure and the electronic property of azidotrimethyltin (ATMT) on monolayer graphene were investigated using scanning tunneling microscopy and core-level photoemission spectroscopy. We also confirmed the n-type doping effect by scanning tunneling spectroscopy and work function ...detailed

Relevant articles and documents

Ein einfaches Verfahren zur Herstellung von Organozinnaziden. Synthese und Struktur der sterisch gehinderten Stannylazide tBu3SnN3 und tBu2Sn(N3)2

Sterically crowded stannyl azides tBunSn(N3)4-n (IIa,b) have been prepared for the first time by the reactions of stannylamines tBunSn(NHR)4-n (Ia,b) with Me3SiN3 (a: n = 3, R = H; b: n = 2, R = tBu).The novel compounds were characterized by NMR (1H, 13C) and mass spectroscopy and their molecular structure determined by X-ray crystallography (IIa: space group P21/m, Z = 2; IIb: space group P21/n, Z = 4). Keywords: Tin; Stannyl azides; Synthesis; X-ray structure

Substituted imidazo-fused 6-membered heterocycles as angiotensin II antagonists

Substituted Imidazo-fused 6-membered heterocycles of structural formula: STR1 wherein A, B, C, and D are independently carbon atoms or nitrogen atoms are angiotensin II antagonists useful in the treatment of hypertension and congestive heart failure.

SUBSTITUTED PYRAZOLOPYRIMIDINES AS ANGIOTENSIN II ANTAGONISTS

Novel substituted pyrazolopyrimidines of formula (I) which are useful as angiotensin II antagonists, are disclosed. STR1