111865-93-1

Basic information

• Product Name: Ethyl, 2-(4-chlorophenyl)-
• CAS NO: 111865-93-1
• Molecular Formula: C8H8Cl
• Molecular Weight: 139.605
• Mol File: 111865-93-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethyl, 2-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl, 2-(4-chlorophenyl)-(111865-93-1)
• EPA Substance Registry System: Ethyl, 2-(4-chlorophenyl)-(111865-93-1)

Safety Data

• Hazardous Substances Data: 111865-93-1(Hazardous Substances Data)

Upstream product

• 2019-34-3 3-(4-chlorophenyl)propanoic acid 

Relevant articles and documents

Electron Spin Resonance Studies. Part 71. Side-chain Oxidation Pathways in the Reactions of .OH and SO4-. with Some Phenyl-substituted Carboxylic Acids, their Anions, and Some related Compounds

A series of arene radical-cations has been generated in situ by the reactions of methylbenzene, phenylethanoic acid, and some derivatives and cyclic analogues with both SO4-. and .OH (the latter in acid solution).The results are interpreted in terms of a variety of subsequent rapid reactions including hydration, deprotonation (to give benzylic radicals), and fragmentation (decarboxylation: for a series of radical-zwitterions +.Ar(CH2)nCO2- (n=1-3) decarboxylation (k >/= 1E9 dm3 mol-1 s-1) appears to proceed via direct intramolecular elecron-transfer, though in some cases formation of a discrete ?-bonded intermediate cannot be ruled out.